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| Research Domain： |
Organic and Physical Chemistry |
| Keyword： |
John I. Brauman |
| Research Production： |
Principal Research Interests
Our research is directed towards understanding how molecules react and the factors that determine the rates and products of chemical reactions. The principal areas of research involve the spectroscopy, photochemistry, reaction dynamics, and reaction mechanisms of ions in the gas phase.
The primary experimental technique used in our research is Ion Cyclotron Resonance (ICR) spectroscopy. We have assembled continuous wave, pulsed, and Fourier-transform instruments. These are coupled with a variety of light sources, including conventional arc lamp/monochromator, argon ion/dye laser/Ti-Sapphire laser, cw CO2 infrared laser, and pulsed TEA CO2 infrared lasers.
Among our current projects are attempts to understand the basis of gas-phase ion reaction dynamics. In particular, we are developing statistical and other models for reaction rates. We make use of the analysis of potential surfaces, for example, to define and characterize nucleophilicity in negative ion reactions without solvent. We are attempting to understand the nature of steric effects and hydrogen bonding and the effects of solvent on these phenomena. We make use of multiple photon infrared absorption to activate reactants or possible intermediates in reactions and observe their unimolecular decomposition.
Finally, we use visible photons to effect detachment of electrons from negative ions. By studying the details of the electron photodetachment process (onsets, threshold shapes, resonances, fine structure, etc.) we learn about electron affinities, electronic structure in ions, excited electronic states in ions, and vibrational structure and spin orbit splitting (or triplet-singlet splitting) in the final state neutrals. |
| Remarks： |
J. G. Jackson-C. J. Wood Professor of Chemistry (b. 1937)
B.S., 1959, Massachusetts Institute of Technology; Ph.D., 1963, University of California at Berkeley
ACS Award in Pure Chemistry, 1973; National Academy of Sciences, 1976; Harrison Howe Award, 1976; American Academy of Arts and Sciences, 1976; Dean's Award for Distinguished Teaching, 1976; Guggenheim Fellow, 1978-79; ACS James Flack Norris Award in Physical Organic Chemistry, 1986; ACS Arthur C. Cope Scholar Award, 1986; R.C. Fuson Award, 1986; Honorary Fellow, California Academy of Sciences, 1991; National Academy of Sciences Award in Chemical Sciences, 2001; Linus Pauling Award, 2002; National Medal of Science Award, 2002; Willard Gibbs Medal, 2003.
Organic and Physical Chemistry
Work Phone:(650) 723-3023
Fax:(650) 725-0259
Work Address:Department of Chemistry
Stanford, California, 94305-5080
Title:J.G. Jackson and C.J. Wood Professor of Chemistry |
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Promulgator Info |
| Full name: |
administrator |
| Country: |
CN |
| City: |
Dalian |
| Company Name: |
teloon Soft Strategy Co.,LTD |
| Homepage: |
http://www.hichem.com |
| E-mail: |
reply |
| Phone: |
86-411-82811662 |
| Fax: |
86-411-82819667 |
| Company Address: |
26 Renmin Road ,Dalian China |
| Zip/Postal Code: |
116001 |
| Introduction: |
As a professional E-information service platform with authoritative news and reports in chemical industry of chinese export and import market.Hichem has been received universally and praised highly since its established in 2001.In 2003,by joint effort of teloon chemicals and teloon soft strategy company(TSSC),Hichem team endeavored to recomposition the site ascribed to market requirement as well as offering our better service.Hichem focused on business to biusiness of new chemicals,fine chemicals,high chemicals and special chemicals.So naturally it is the very one-stop website for chemical information.Our sellers worldwide and build global on-line trade in the chemical industry. |
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