Faculty Information, Institute for Chemical Research, Kyoto University     [ English | Japanese ] YAMAGO, Shigeru Division of Materials Chemistry - Chemistry of Polymeric Functionality Materials - Professor Doctor of Science E-mail: yamago@scl.kyoto-u.ac.jp Tel: 0774-38-3060 Fax: 0774-38-3067
Academic career 1991.3 Graduated from Dr. Course, Tokyo Institute of Technology 1991.3 D. Sc, Tokyo Institute of Technology 1991.4 Assistant Professor, Tokyo Institute of Technology 1995.4 Assistant Professor, Kyoto University 1997.5 Associate Professor, Kyoto University 2003.4 Professor, Osaka City University 2006.4 Professor, Kyoto University Research field Synthetic Organic Chemistry Synthetic Polymer Chemistry Current research 1. Development of novel synthetic radical reaction and living radical polymerization 2. Development of highly controlled radical reaction using organoheteroatom compounds 3. Development of oligosaccharide synthesis based on control of carbocationic speceis Selected publications Kwak, Y.; Goto, A.; Fukuda, T.; Kobayashi, Y.; Yamago, S., A Systematic Study on Activation Processes in Organotellurium-Mediated Living Radical Polymerizations (TERPs) of Styrene, Methyl Methacrylate, Methyl Acrylate, and Vinyl Acetate Yamago, S., The Development of Organotelluriu-Mediated and Organostibine-Mediated Living Radical Polymerization Reactions Yamada, T.; Kinjyo, S.; Yoshida, J.; Yamago, S., Highly Efficient Synthesis of Oligo-N-acetylglucosamines by Iterative Glycosylation of Di- and Tetrachlorophtaloyl Protected Thioglycosides Yamago, S.; Yamada, T.; Ito, H.; Hara, O.; Mino, Y.; Yoshida, J., Combinatorial Synthesis of Oligosaccharide Library by b-Bromoglycoside-Mediated Iterative Glycosylation of Selenoglycosides. Rapid Expansion of Molecular Diversity from Simple Building Blocks Yamago, S.; Satoh, A.; Tokuyama, H.; Fukuyama, T., Synthesis of 2,3-Dialkyl-substituted Indoles from 2-Alkenylphenylisonitriles and Imines by Silyltelluride- and Tinhydride-Mediated Sequential Radical Reactions Kwak, Y.; Goto, A.; Fukuda, T.; Yamago, S.; Ray, B., Mechanism and Kinetics of Organostibine-Mediated Living Radical Polymerization of Styrene Yamago, S.; Fujita, K.; Miyoshi, M.; Kotani, M.; Yoshida, J., Stereoselective Synthesis of Multisubstituted Alkenes via Conformationally Labile Alkenyllithium Species Yamago, S., Invention of Organotellurium and Organostibine Mediators for Highly Controlled Degenerative Transfer Polymerization Mutoh, Y.; Murai, T.; Yamago, S., Acyclic Telluroiminium Salts: Isolation and Characterization Iida, K.; Yoshida, J.; Tada, T.; Yoshizawa, K.; Kwak, Y.; Goto, A.; Fukuda, T., 76. ¡ÈHighly Versatile Organostibine Mediators for Living Radical Polymerization¡É Yamago, S.; Yamada, T.; Maruyama, T.; Yoshida, J., Iterative Glycosylation of 2-Deoxy-2-Amino-Thioglycosides and Its Application to Combinatorial Synthesis of Linear Oligoglucosamines Yamago, S., Novel Group-Transfer Radical Reactions with Organotelluriums Goto, A.; Kwak, Y.; Fukuda, T.; Yamago, S.; Iida, K.; Nakajima, M.; Yoshida, J., Mechanism-Based Invention of High-Speed Living Radical Polymerization Using Organotellurium Compounds and Azo-Initiators Nakamura, M.; Wang, X. Q.; Isaka, M.; Yamago, S.; Nakamura, E., Synthesis and [3 + 2] Cycloaddition of 2,2-Dialkoxy-1-methylenecyclopropane: 6,6-Dimethyl-1-methylene-4,8-dioxaspiro[2.5]octane Yamago, S.; Iida, K.; Nakajima, M.; Yoshida, J., Practical Protocols for Organotellurium-Mediated Living Radical Polymerization (TERP) by in situ Generated Initiators from AIBN and Ditellurides Yamago, S.; Miyazoe, H.; Nakayama, T.; Miyoshi, M.; Yoshida, J., A New Diversity Oriented Synthesis of a-Amino Acids Derivatives by Silyltelluride-Mediated Radical Coupling Reaction of Imines and Isonitriles Yamago, S.; Iida, K.; Yoshida, J., Organotellurium Mediated Living Radical Polymerization (TERP) Yamago, S.; Yoshida, J., Photochemical Addition of Carbohydrate Molecules Yamago, S.; Kokubo, K.; Hara, O.; Masuda, S.; Yoshida, J., Electrochemistry of Chalcogenoglycosides. Rational Design of Iterative Glycosylation Based on Reactivity Control of Glycosyl Donors and Acceptors by Oxidation Potentials Yamago, S.; Iida, K.; Yoshida, J., Tailored Synthesis of Structurally Defined Polymers by Organotellurium Mediated Living Radical Polymerization (TERP). Synthesis of Poly(meth)acrylate Derivatives and Their Di- and Triblock Copolymers Yamago, S.; Hashidume, M.; Yoshida, J., A New Synthetic Route to Substituted Quinones by Radical-Mediated Coupling of Organotellurium Compounds with Quinones Yamago, S.; Miyoshi, M.; Miyazoe, H.; Yoshida, J., Convergent Synthesis of Silylated Allylic Alcohols by a Stereoselective Domino-Sequential Radical Coupling Reaction Yamago, S.; Iida, K.; Yoshida, J., Organotellurium Compounds as Novel Initiators for Controlled/Living Radical Polymerizations. Synthesis of Functionalized Polystyrenes and End-Group Modifications Yamago, S.; Yamada, T.; Nishimura, R.; Ito, H.; Mino, Y.; Yoshida, J., A New Method for the Synthesis of Stannyl Ethers by Acid-Catalyzed Reaction of Alcohols with Allyl Tributylstanane Oka, H.; Yamago, S.; Yoshida, J.; Kajimoto, O., Evidences for Hydroxide Ion Catalyzed Pathway in Ester Hydrolysis in Supercritical Water Yamago, S.; Iida, K.; Yoshida, J., Organotellurium Compounds as Novel Initiators for Controlled/Living Radical Polymerzations Nakamura, E.; Yamago, S., Thermal Reactions of Dipolar Trimethylenemethane Species Yamago, S.; Yamada, T.; Hara, O.; Ito, H.; Mino, Y.; Yoshida, J., A New, Iterative Strategy for Oligosaccharide Synthesis Based on Highly Reactive b-Bromoglycosides Derived from Selenoglycosides Yamago, S.; Iida, K.; Yoshida, J., A New, Practical Synthesis of Organotellurium Compounds from Organic Halides and Silyl Tellurides. Remarkable Effects of Polar Solvents and Leaving Groups Yamago, S.; Miyazoe, H.; Goto, R.; Hashidume, M.; Sawazaki, T.; Yoshida, J., Synthetic and Theoretical Studies on Group-transfer Imidoylation of Organotellurium Compounds. Remarkable Reactivity of Isonitriles in Comparison with Carbon Monoxide in Radical-Mediated Reactions Yamago, S.; Miyazoe, H.; Iida, K.; Yoshida, J., Highly Efficient and Chemoselective Reductive Bis-silylation of Quinones by Silyl Tellurides Yamago, S.; Hashidume, M.; Yoshida, J., Radical-Mediated Synthesis of Substituted Quinones with Organotellurium Compounds Yamago, S.; Miyazoe, H.; Sawazaki, T.; Goto, R.; Yoshida, J., New Synthesis of a-Acylimines and a-Acylamide by Imidoylation of Acyl Radicals with Isocyanides Miyazoe, H.; Yamago, S.; Yoshida, J., New Radical-Mediated Group-Transfer Three Component Coupling of Silyltellurides, Carbonyl Compounds, and Isocyanides Nakamura, M.; Toganoh, M.; Wang, X. Q.; Yamago, S.; Nakamura, E., Intramoleculer [3 + 2] Cycloaddition Reactions of Dipolar Trimethylenemethane Yamago, S.; Yanagawa, M.; Nakamura, E., Thermal Hetero [3 + 2] Cycloaddition of Dipolar Trimethylenemethane to N-Sulfonyl and N-Acyl Imines. Synthesis of g-Amino Acid Derivatives Yamago, S.; Miyazoe, H.; Goto, R.; Yoshida, J., Radical Mediated Imidoylation of Telluroglycosides. Insertion of Isonitriles into Glycosidic CarbonTellurium Bond Yamago, S.; Miyazoe, H.; Yoshida, J., Synthesis of Vinylic C-Glycosides from Telluroglycosides. Addition of Photochemically and Thermally Generated Glycosyl Radicals to Alkynes Yamago, S.; Miyazoe, H.; Yoshida, J., Reversible Generation of Glycosyl Radicals from Telluroglycosides under Photochemical and Thermal Conditions Yamago, S.; Kokubo, K.; Murakami, H.; Mino, Y.; Hara, O.; Yoshida, J., Glycosylation with Telluroglycosides. Stereoselective Construction of a- and b-Anomers Yamago, S.; Furukawa, M.; Azuma, A.; Yoshida, J., Synthesis of Optically Active Dendritic Binaphthols and Their Metal Complexes for Asymmetric Catalysis Yamago, S.; Nakamura, M.; Wang, X.-Q.; Yanagawa, M.; Tokumitsu, S.; Nakamura, E., Thermal Hetero [3 + 2] Cycloaddition of Dipolar Trimethylenemethane to O-Alkyl Oximes. Straightforward Synthetic Routes to Substituted Pyrrolidines and Prolines Nakamura, E.; Yu, Y.; Mori, S.; Yamago, S., Unusually Stable Organomercury Hydrides and Radicals Yamago, S.; Kokubo, K.; Yoshida, J., O-Glycosidation of Telluroglycoside by Electrochemical Oxidation Yamago, S.; Takeichi, A.; Nakamura, E., Synthesis of Dimethyleneketene Acetals and Their [2 + 2] Cycloaddition to Olefins and [60]Buckminsterfullerene as Cyclopropanecarboxylate Synthons Yamago, S.; Kokubo, K.; Masuda, S.; Yoshida, J., Practical Synthesis of Telluroglycosides Nakamura, E.; Tokuyama, H.; Yamago, S.; Shiraki, T.; Sugiura, Y. Bull. Chem. Soc., Jpn.., 32. "Biological Activity of Water-Soluble Fullerenes. Structurel Dependence of DNA Cleavage, Cytotoxicity and Enzyme Inhibitory Activities Including HIV-Protease Inhibition" Irie, K.; Nakamura, Y.; Ohigashi, H.; Tokuyama, H.; Yamago, S.; Nakamura, E., Photocytotoxicity of Water-soluble Fullerene Derivatives Yamago, S; Nakamura, E., Cycloaddition of Dipolar Trimethylenemethane to C70 Promoted by a Trace Amount of Water Yamago, S.; Yanagawa, M.; Mukai, H.; Nakamura, E., Tertiary Phosphines, P-Chiral Phosphinites and Phosphonic Acid Esters Bearing Fullerene Subtituent. Metal Complexes and Redox Properties Yamago, S.; Ejiri, S.; Nakamura, E., A Concise Synthetic Route to Cyclopentenes by [3 + 2] Cycloaddition of Dipolar Trimethylenemethane to Acetylenes Yamada, T.; Uekusa, H.; Ohashi, Y.; Yamago, S.; Wang, X.-Q.; Nakamura, E., cis- and trans-Dimethyl Spiro[(4',4'-dimethyl-2',6'-dioxacyclohexane)-1',3- (4-methylenebicyclo[3.3.0]octane]-2,2-dicarboylate Yamago, S.; Tokuyama, H.; Nakamura, E.; Kikuchi, K.; Kananishi, S.; Sueki, K.; Nakahara, H.; Enomoto, S.; Ambe, F., In Vivo Biological Behavior of Water-Misible Fullerenes. 14C-Labeling, Absorption, Distribution, Excretion and Acute Toxicity Matsumoto, M.; Tachibana, H.; Azumi, R.; Tanaka, M.; Nakamura, T.; Yunome, G.; Abe, M.; Yamago, S.; Nakamura, E., Langmuir-Blogett Film of Amphilic C60 Carboxylic Acid Yamago, S.; Yanagawa, M.; Nakamura, E., Tertiary Phosphines and P-Chiral Phosphinites Bearing Fullerene Subtituent Yamago, S.; Ejiri, S.; Nakamura, E., Hydrostannation of Cyclopropene. Strain-Driven Radical Addition Reaction Yamago, S.; Takeichi, A.; Nakamura, E., Synthesis and [2 + 2] Cycloaddition of Dimethyleneketene Acetal. Reaction with C60 and Facile Hydrolyisis of the C-C Bond Connected to C60 Yamago, S.; Yanagawa, M.; Nakamura, E., Tertiary Phosphines and P-Chiral Phosphinites Bearing Fullerene Substituent Yamago, S.; Tokuyama, H.; Nakamura, E.; Prato, M.; Wudl, F., Chemical Derivatization of Organofullerenes through Oxidation, Reduction, C-O and C-C Bond Forming Reactions Tokuyama, H.; Yamago, S.; Nakamura, E.; Shiraki, T.; Sugiura, Y., Photo-induced Biological Activity of Fullerene Carboxylic Acid Yamago, S.; Ejiri, S,; Nakamura, M.; Nakamura, E., A Single Electron Transfer Pathway in the [3 + 2] Cycloaddition of Dipolar Trimethylenemethane with Olefins Prato, M.; Suzuki, T.; Foroudian, H.; Li, Q.; Khemani, K.; Wudl, F.; Leonetti, J.; Little, R. D.; White, T.; Rickborn, B.; Yamago, S.; Nakamura, E., [3 + 2] and [4 + 2] Cycloaddition of C60 Yamago, S.; Tokuyama, H.; Nakamura, E.; Prato, M.; Wudl, F., Synthesis of Organic Derivatives of Fullerenes Yamago, S.; Nakamura, E., Regio-and endo-Stereoselective [3 + 2] Cycloaddition of Dipolar Trimethylenemethanes to Electron-Deficient Olefin Nakamura, E.; Yamago, S.; Ejiri, S.; Dorigo, A. E.; Morokuma, K., Reversible Generation of Trimethylenemethanes by Mild Thermolysis of Dialkoxy Methylenecyclopropanes Yamago, S.; Machii, D.; Nakamura, E., Simple Diasteroselectivity of the Aldol Reaction of Persubstituted Enolates. Stereoselective Construction of Quaternary Centers Yamago, S.; Nakamura, E., Thermal Hetero [3 + 2] Cycloaddition Approach to Functionalized Tetrahydrofurans Isaka, M.; Matsuzawa, M.; Yamago, S.; Ejiri, S.; Miyachi, Y.; Nakamura, E., Applications of Metalated Cyclopropenone Ketals in General Synthesis of Cyclopropenoes. An Efficient Synthesis of the Antibiotic Penitricin Yamago, S.; Nakamura, E., Use of Methylenecyclopropanone Ketals for Cyclopentane Synthesis. A New Efficient Thermal [3 + 2] Cycloaddition Yamago, S.; Nakamura, E., Synthesis of Propellanes by "Exocyclic" Transannular Cycloaddition of Olefinic Methylenecyclopropanes Yamago, S.; Nakamura, E., Synthesis of [3.3.3] Propellanes by 'Exocyclic' Transannular Cycloaddition of Olefinic Methylenecyclopropanes Nakamura, E.; Yamago, S.; Machii, D.; Kuwajima, I., Stereochemistry of the Fluoride Catalyzed Aldol Reaction of Enol Silyl Ethers. Evidences for Another Non-Chelate Transitionstate
Update: May 08, 2006